为研究导电聚苯胺衍生物与金属离子在溶液中形成的配合物的荧光性质,采用化学氧化法合成了导电聚合物聚N-[5-(8-羟基喹啉)甲基]苯胺(PNQMAn),对本征态和盐酸掺杂的聚N-[5-(8-羟基喹啉)甲基]苯胺在溶液中与Al^3+形成的配合物的二维和三维荧光光谱进行了表征.结果表明,PNQMAn无论掺杂与否,在溶液中与铝离子形成的配合物都具有较好的荧光性.
To study the fluorescence properties of the conducting polyaniline (PAn) derivatives and the corresponding complexes in solution with metal ion, a novel conducting polymer of poly N-[5-(8-quinolinol)yl-methyl ] -aniline (PNQMAn) was synthesized by chemical oxidation. 2- and 3-dimension fluorescent spectrum of the complex of intrinsic and doped PNQMAn coordinated with Al^3+ in solution were studied. The result shows that, whether doped or not, the complex of PNQMAn coordinated with Al3^+ in solution has better fluorescence.