以Zn(NO3)2·2H2O,CO(Nn2h,Eu(NO3)3·6H2O和LiNO3·2H2O为原料,采用均相共沉淀法制备了Eu,Li共掺的纳米ZnO:(Eu,Li)荧光粉。用扫描电镜、x射线衍射、热重一差示扫描量热分析等表征了样品的结构、形貌。研究了Eu与Li的摩尔比和煅烧温度对样品的发光性能的影响。结果表明:合成的ZnO:(Eu,Li)粉体具有六方纤锌矿结构的ZnO晶型,粒度分布均匀,粒径尺寸为20-40um。当Eu与Li的摩尔比为3:1时,700℃下煅烧2h的样品发光强度最高。在发射光谱中样品的发射峰位于570-620nm,其发射主峰位于611nm处,对应于Eu的^5D0→^7F2跃迁。
Eu, Li co-doped ZnO:(Eu, Li) nanopowders were synthesized by the homogeneous co-precipitation method using Zn(NO3)E-2H2O, CO(NH2)2, Eu(NO3)3·6H2O and LiNO3·2H2O as raw materials. The structure and morphology of the samples were characterized by scanning electron microscopy, X-ray diffraction and thermogravimetry-differential scanning calorimetry analysis. The effects of the mole ratio of Eu to Li and calcination temperature on photoluminescence properties of samples were investigated. The results show that the ZnO:(Eu, Li) nanopowder is a pure hexagonal wurtzite structure of ZnO crystal. The particle sizes of the nanopowders are distributed uniformly in the range of 20-40 nm. When the mole ratio of Eu to Li is 3:1, the luminescence intensity of the nanopowder sample calcined at 700℃ for 2 h increases to the maximum. The emission peak of the nanopowders in the emission spectra are located at 570-620 nm, and the maximum emission peak is at 611 nm with 463 nm excitation, corresponding to the ^5D0→^7F2 transition of Eu.