位置:成果数据库 > 期刊 > 期刊详情页
Synthesis, Luminescence and Electrochemical Properties of Two Phenothiazine Derivatives
  • ISSN号:1001-604X
  • 期刊名称:《中国化学:英文版》
  • 时间:0
  • 分类:TQ463.53[化学工程—制药化工]
  • 作者机构:[1]Department of Chemistry, Anhui University, Hefei, Anhui 230039, China, [2]State Key Laboratory of Crystal Materials, Shandong University, Jinan, Shandong 250100, China, [3]State Key Laboratory of Coordination Chemistry, Nanfing University, Nanfing, Jiangsu 210093, China
  • 相关基金:Project supported by the National Natural Science Foundation of China (Nos. 50272001, 50335050), Person with Ability Foundation of Anhui Province (No. 2002Z021) and the Department of Education of Anhui Province (No. 2004KJ020).
中文摘要:

合成,光和二新奇 phenothiazine 衍生物的电气化学的性质被介绍,它展出好一个光子荧光排放。量收益和他们的溶剂效果详细被学习。复合 3,7 二度(2-4-imidazolylbenzylidenehydrazonoethyl )-(0-ethylphenothiazine)(5 ) 被用作一个有效开始者,二光子的荧光系列在 800 nm fs 激光脉搏下面被调查,测量二光子的吸收剖面图是 18 桴 ? 慢吗?

英文摘要:

The synthesis, luminescence and electrochemical properties of two novel phenothiazine derivatives were presented, which exhibit good one-photon fluorescence emission. The quantum yields and solvent effects of them were studied in detail. Compound 3,7-bis(2-4'-imidazolylbenzylidenehydrazonoethyl)-(0-ethylphenothiazine) (5) was used as an effective initiator, of which two-photon fluorescence spectra were investigated under 800 nm fs laser pulse and the measured two-photon absorption cross-section was 18 × 10^-50 cm^4·s per photon. Two-photon initiated polymerization microfabrication experiments were carried out. X-ray diffraction analyses revealed that the shape of the compound 3,7-bis(2-pyrid-4'-ylmethylidenehydrazonoethyl)-(0-ethylphenothiazine) (4) looks like a butterfly with nearly planar wings. The dihedral angle of the two benzene rings is 37.6° and there is an obvious π-π stacking interaction between the molecules in the crystal.

同期刊论文项目
期刊论文 72 会议论文 12
同项目期刊论文
期刊信息
  • 《中国化学:英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编:
  • 地址:上海市枫林路354号中科院上海有机化学研究所
  • 邮编:200032
  • 邮箱:
  • 电话:021-54925243
  • 国际标准刊号:ISSN:1001-604X
  • 国内统一刊号:ISSN:31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175