对硝基苯胺和对碘苯乙醚经取代反应制得4'-硝基-(4-乙氧基苯)苯胺(3);3与对氟苯甲醛经取代反应制得含乙氧基的脂溶性中间体4-[(4'-乙氧基苯基)(4″-硝基苯基)氨基]苯甲醛(5);5与4-N,N-二乙基胺基苄基三苯基鏻盐经Witting成烯反应后经Pd/C催化、水合肼还原合成了新化合物4-[4'-(二乙基氨基)苯乙烯基]-N-(4″-乙氧基苯基)-N-(4-氨基苯基)苯胺,其结构经1H NMR,IR,MS和元素分析表征。
4-Ethoxy-N-(4-nitrophenyl)aniline(3) was prepared by substitution reaction of parani- troaniline with iodobenzene ether. 4- [ (4-Ethoxyphenyl) (4-nitrophenyl) amino ] benzaldehyde ( 5 ) was obtained by substitution reaction of 3 with fluorobenzaldehyde. A novel triphenylamine deriva- tive, N1-{ 4[ 4-( diethylamino ) styryl] phenyl } -N1-( 4-ethoxyphenyl ) -N4-( pyridin-4-ylmethylene ) benzene-1,4-diamine, was synthesized by Witting reaction of 5 with N,N-diethyl-4-E (iodotripheny- lphosphoranyl) methyl] aniline and then reduced by hydrazine hydrate using Pd/C as the catalyst. The structure was characterized by 1H NMR, IR, MS and elemental analysis.