以三苯胺和8-羟基喹啉为原料,经甲酰化、Wittig-honor及取代等5步反应合成了一种新型的喹啉类化合物——8-[N-{4-[4-(二苯基氨基)苯乙烯基]苯基}]乙酰氨基氧基喹啉(1),其结构经1H NMR,13C NMR,IR和ESI-MS表征.用紫外可见光谱和荧光光谱研究了1的光学性质,结果表明:1的λmax在300 nm,375 nm;在375 nm激发波长激发下,1在乙醇中的最大荧光发射峰位于450nm.
A novel quinoline derivative, 8-[ N-{ 4-[4-(diphenyl amine) styryl] phenyl } ] acetyl amino oxyl quinoline (1), was synthesized from triphenylamine and 8-hydroxylquinoline by formylation, Wittig-hornor reaction, substitution reaction and so on. The structure was characterized by 1H NMR, 13C NMR, IR and ESI-MS. The optical properties of 1 were investigated by UV-Vis and fluorescence spectroscopies. The results showed that λmax of 1 is 300 nm and 375 nm. The maximum peak of I was at 450 nm under excitation wavelengths of 375 nm in EtOH.