以乙醇为溶剂,用姜黄素、溴乙烷和稀土盐等为原料,合成了二乙基姜黄素镧(Ⅲ)和钐(Ⅲ)配合物,通过IR,1HNMR,MS和元素分析对目标化合物进行了结构表征;并对它们的紫外可见电子光谱、单、双光子荧光光谱进行了研究,同时采用1064 nm皮秒脉冲激光通过Z扫描技术拟合得到了双光子吸收系数和吸收截面。结果显示目标物具有较好的光学性质和双光子吸收截面。
Diethylcurcumin lanthanum(Ⅲ) and samarium(Ⅲ) complexes were synthesized by curcumin,ethylbromide and rare earth salts as the starting material and ethanol as solvent.Their structures were characterized by IR,1HNMR,MS and elemental analysis.The UV-Vis absorption spectra,and one and two-photon fluorescence spectra had been investigated.The TPA coefficients of β and cross-section σ of the complexes were obtained by 1064 nm picosecond laser beam via the open-aperture Z-scan technique.The results showed that the compounds had good optical properties and two-photon absorption cross-sections.