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化学气相浸渗2D Cf/(SiC-C)复合材料的微观结构与强韧性
  • ISSN号:1000-324X
  • 期刊名称:《无机材料学报》
  • 时间:0
  • 分类:TB332[一般工业技术—材料科学与工程] TQ174[化学工程—陶瓷工业;化学工程—硅酸盐工业]
  • 作者机构:[1]西北工业大学超高温结构复合材料国家重点实验室,西安710072
  • 相关基金:国家杰出青年科学基金(50425208)
中文摘要:

采用等温等压化学气相浸渗法(ICVI)制备了二维碳纤维增韧碳化硅碳二元基复合材料(2D Cf/(SiC-C)).利用扫描电镜(SEM)和背散射电子成像(BSE)研究了其基体的微观结构, 并与二维碳纤维增韧碳化硅陶瓷基复合材料(2D Cf/SiC)比较了室温力学性能和断口形貌.结果表明:2D Cf/(SiC-C)复合材料的基体是由SiC与热解碳(PyC)组成的多层结构, PyC基体层分布均匀而连续, 且与SiC基体层结合紧密.纤维束内部PyC基体层较厚的2D Cf/(SiC-C)复合材料具有较高的强韧性, 其拉伸强度、断裂应变、断裂韧性和断裂功分别比2D Cf/SiC复合材料的提高了3%、142%、22%和58%.SiC与PyC组成的多层基体使2D Cf/(SiC-C)复合材料的纤维在拔出过程中发生了两次集中拔出, 且第一次集中拔出的纤维对复合材料的强韧性起主要作用.

英文摘要:

Two dimensional carbon fiber-reinforced silicon carbide-carbon binary matrix composites (2D Cf/(SiC-C)) were fabricated by means of isothermal and isobaric chemical vapor infiltration (ICVI). The matrix structures of the 2D Cf/(SiC-C) composites were characterized by the backscattered electron imaging (BSE) of scanning electron microscope (SEM). Furthermore, their room temperature mechanical properties and fracture surfaces were compared with two dimensional carbon fiber-reinforced silicon carbide matrix composite (2D Cf/SiC). The results indicate that the matrices in the 2D Cf/(SiC-C) composites are multilayered structures composed of SiC and PyC layers. The PyC matrix layers are homogeneous and continuous, which are bonding well with SiC matrix layers. The 2D Cf/(SiC-C) composite with a thicker PyC matrix layer in fiber bundles exhibits better mechanical properties. Meanwhile, its tensile strength, failure strain, fracture toughness and fracture work are 3%, 142%, 22% and 58% higher than those of the 2D Cf/SiC composite, respectively. The multilayered matrices composed of SiC and PyC layers, cause the fibers in the 2D Cf/(C-SiC) composites to pull out twice in a concentrated mode. Moreover, the first pull-out fibers play a leading role in enhancing the strength and toughness.

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期刊信息
  • 《无机材料学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院上海硅酸盐所
  • 主编:郭景坤
  • 地址:上海市定西路1295号
  • 邮编:200050
  • 邮箱:wjclxb@mail.sic.ac.cn
  • 电话:021-52411302
  • 国际标准刊号:ISSN:1000-324X
  • 国内统一刊号:ISSN:31-1363/TQ
  • 邮发代号:4-504
  • 获奖情况:
  • 获"中国百种杰出学术期刊"称号
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),瑞典开放获取期刊指南,中国北大核心期刊(2000版)
  • 被引量:21274