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L-(-)-α-苯乙胺类立方烷结构2-萘甲酸二聚体盐的晶体结构
  • 期刊名称：感光科学与光化学
  • 时间：0
  • 页码：37-41
  • 语言：中文
  • 分类：O64[理学—物理化学;理学—化学]
  • 作者机构：[1]中国科学院理化技术研究所有机光电功能材料与分子工程学重点实验室,北京100080, [2]中国科学院研究生院,北京100039
  • 相关基金：科技部国家重点基础研究发展规划项目（2006CB806105,G2007CB808004）;国家自然科学基金资助项目（20333080,20332040,20472091）;中科院基础局资助项目.
  • 相关项目：芳烃三羰基锰络合物的光化学反应及其在合成化学中的应用
作者： 雷蕾|吴骊珠|佟振合|张丽萍|武小玲|
关键词： L-(-)-α-苯乙胺, 类立方烷结构2-萘甲酸二聚体, C2对称性, L-（-）-α-phenyl ethylamine, cubane-like dimer of carboxylic 2-naphthoate acid, C2 symmetry
中文摘要：

L-（-）-α-苯乙胺与消旋的类立方烷结构2-萘甲酸二聚体相互作用形成铵盐,其晶体结构表明,L-（-）-α-苯乙胺与类立方烷结构2-萘甲酸二聚体作用形成的铵离子通过氢键N2A—HN2B…O5A和N1A—HN1A…O3A与类立方烷结构2-萘甲酸二聚体结合在一起.同时类立方烷结构2-萘甲酸二聚体的两个对映异构体之间也存在分子间氢键O1A—H1AA…O6A和O1B—H1AB…O6B.这些氢键将类立方烷结构2-萘甲酸二聚体的两个对映异构体连在同一个晶胞中,呈现两条分子链状堆积.

英文摘要：

L-（-）-α-Phenyl ethylamine was reacted with cubane-like dimer of carboxylic 2-naphthoate to afford L-（-）-α-phenyl ethylammonium cubane-like dimer of carboxylic 2-naphthoate with high yield.Crystal structural analysis demonstrates that the hydrogen bonding of N2A—HN2B…O5A and O1A—HN1A…O3A are responsible for the crystal packing,in which N2A—HN2B…O5A connects L-（-）-α-phenyl ethylammonium cation and cubane-like dimer of carboxylic 2-naphthoate.Intermolecular hydrogen bonding of O1A—H1AA…O6A and O1B—H1AB…O6B directs the assembly of two enatiomers of cubane-like dimer of carboxylic 2-naphthoate acid.

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