欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
采用熔融淬冷法制备了系列Ge3Se5Te2Snx （x=0、0.4、0.8、1.2、1.6、2.0, mol%）硫系玻璃。采用Ｘ射线衍射（XRD）图谱、差示扫描量热曲线（DSC）、可见/近红外光谱、傅里叶红外（FTIR）光谱、显微拉曼光谱等手段对玻璃的物化性能及结构进行表征, 研究发现Sn的引入导致Ge-Se-Te玻璃系统物化性能的变化： 玻璃的转变温度Tg降低、红外截止波长发生红移, 并有效地降低了杂质吸收峰对样品红外透过率的影响。利用Philips网络约束理论计算的玻璃平均配位数及拉曼光谱的变化, 讨论了引入Sn对Ge-Se-Te玻璃的影响。
英文摘要：
A series of Ge3Se5Te2Snx（x=0, 0.4, 0.8, 1.2, 1.6, 2.0, mol%） chalcogenide glasses were prepared by traditional melt-quenching method. The physiochemical properties and structure changes of glasses were characterized by employing the techniques of X-ray diffraction （XRD）, differential scanning calorimetry （DSC）, visible-near IR spectrum, Fourier transform infrared spectrum （FTIR）, and Raman spectroscope. Physiochemical properties of Ge-Se-Te glasses change with the addition of Sn, including glass transition temperature （Tg） decreacing and infrared cut-off wavelength shifting toward long wavelength which effectively inhibits the absorption peaks of impurities in the mid-IR spectral region. In addition, the origination behind these phenomena is discussed by the average coordination number calculated from Philips network-constrained theory and structural evolution of Raman spectra.
同期刊论文项目
同项目期刊论文
Glass formation and third-order optical nonlinear characteristics of bismuthate glasses within Bi2O3
Competitive Phase Separation to Controllable Crystallization in 80GeS2 center dot 20In2S3 Chalcogeni
Performance improvement of transparent germanium-gallium-sulfur glass ceramic by gold doping for thi
Competitive Phase Separation to Controllable Crystallization in 80GeS 2·20In 2S 3 Chalcogenide Glass
Modeling and simulation of mid-IR amplifying characteristics of Tm3+-doped chalcogenide Photonic Cry
Tapered chalcogenide-tellurite hybrid microstructured fiber for mid-infrared supercontinum generatio
Mechanism of the enhancement of mid-infrared emission from GeS2-Ga2S3 chalcogenide glass-ceramics do
期刊信息
位置：