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Corrosion behavior of aluminum alloys in Na2SO4 solution using the scanning electrochemical microscopy technique
  • ISSN号:1672-9242
  • 期刊名称:《装备环境工程》
  • 时间:0
  • 分类:TG146.21[金属学及工艺—金属材料;一般工业技术—材料科学与工程;金属学及工艺—金属学] O613.71[理学—无机化学;理学—化学]
  • 作者机构:[1]School of Materials Science and Engineering, University of Science and Technology Bei.jing, Beijing 100083, China, [2]Beijing Key Laboratory for Corrosion, Erosion and Surface Technology, Beijing 100083, China
  • 相关基金:This study was financially supported by the National Natural Science Foundation of China (No.50499331) and the National Science and Technology Basic Conditional Platform (No.2005DTA 10400). Acknowledgement We thank Guo-zhe Meng in Harbin Engineering University for providing the M370 electrochemical workstation facilities.
中文摘要:

铝合金的腐蚀行为 1060 并且在 10 公里 Na2SO4+5 公里 KI 答案的 2A12 被扫描电气化学的显微镜学(SECM ) 并且扫描电子显微镜学(SEM ) 调查。潜在的地形学和腐蚀形态学结果证明样品的潜力随沉浸时间的增加出现在一样的区域变化上。腐蚀区域变得大,并且潜力变得更否定。2A12 合金表面的腐蚀潜力比 1060 铝的,和 2A12 合金容易成为腐蚀剂低。这是在一些金属间化合的粒子(淘气鬼) 的边界区域的那优先的溶解发生的原因,因为不同潜力,不同溶解行为与淘气鬼的不同类型被联系。

英文摘要:

The corrosion behavior of aluminum alloys 1060 and 2A12 in a 10 mM Na2SO4+5 mM KI solution was investigated by scanning electrochemical microscopy (SECM) and scanning electron microscopy (SEM). The potential topography and corrosion morphology results show that the potential of the sample surface over the same area changes with the increase of immersion time. The corrosion area becomes large, and the potential becomes more negative. The corrosion potential of the 2A12 alloy surface is lower than that of 1060 aluminum, and 2A12 alloy becomes easily corrosive. This is the reason that preferential dissolution in the boundary region of some intermetallic particles (IMPs) occurs and different dissolution behaviors are associated with different types of IMPs because of different potentials.

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期刊信息
  • 《装备环境工程》
  • 中国科技核心期刊
  • 主管单位:中国兵器装备集团公司
  • 主办单位:中国兵器工业第五九研究所 国防科技工业自然环境试验研究中心
  • 主编:唐伦科
  • 地址:重庆市石桥铺渝州路33号
  • 邮编:400039
  • 邮箱:hjgczzb@163.com
  • 电话:023-68792835
  • 国际标准刊号:ISSN:1672-9242
  • 国内统一刊号:ISSN:50-1170/X
  • 邮发代号:78-7
  • 获奖情况:
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  • 被引量:2831