利用熔融共混法制备了不同氯化锌(ZnCl2)用量下的聚酰胺6(PA6)/ZnCl2复合材料。分别采用差示扫描量热仪(DSC)、动态力学分析仪(DMA)、电子拉伸机等对不同ZnCl2用量下PA后/ZnCl2复合材料的结晶行为及力学性能进行了研究。结果表明:随着ZnCl2用量的增加,PA6/ZnCl2复合材料的拉伸强度和弯曲强度均呈现先增大后减小的趋势。当ZnCl2质量分数为5%时,复合材料的拉伸强度和弯曲强度分别达到最大值70.39MPa和64.71MPa,较纯PA6分别增加了7.5%和降低了28%;随着ZnCl2用量的增加,PA6/ZnCl2复合材料的玻璃化转变温度逐渐增大,结晶能力下降,结晶度减小,结晶度由原来的34%变为13%。
PA6/ZnCl2 composites with different ZnCl2 contents were prepared by melt blending method. PA6/ZnCl2 composites were characterized by differential scanning calorimetry (DSC), Dynamic mechanical analyzer(DMA)and electronic tensile machine. The crystallization behavior and mechanical properties of PA6 / ZnCl2 composites with different ZnClz contents were studied. The results show that tensile strength and flexural strength of PA6/ZnCl2 composites increase first and then decrease with the increase of ZnCl2 content. When the mass fraction of ZnCl2 is 5% ,the tensile strength and flexural strength of PA6/ZnCl2 composites respectively reach the maximum value of 70. 39 MPa and 64. 71 MPa, compared with pure PA6 increased by 7. 50/oo and decreased by 28%. With the increasing of ZnCl2 content,the glass transition temperature of PA6/ZnCl2 composite gradually increases,while crystallization ability and the crystallinity decreases. The erystallinity decreases from 34% to 13%.