通过硅氢化反应,在催化剂氯铂酸作用下,使聚氢基硅氧烷(PMHS)上的si—H键与十一烯酸(uA)上的烯基发生加成,过量的si.H键与聚烯基硅氧烷(PMVS)反应,合成了含羧基的十一烯酸一硅橡胶共聚物(UA—CO—PDMS);接着利用uA—CO.PDMS表面的羧基和多巴胺(DA)发生胺化反应,制得了多巴胺修饰的硅橡胶(DA,I,A_CO—PDMs)。结果表明,经十一烯酸改性并在表面修饰了多巴胺的硅橡胶,与水和甘油的接触角由1070,110。分别减小到44.69。,49.500,表面能为55.05mJ/m2.提高了4.7倍。
By hydrosilation reaction, the chloroplatinic acid - catalyzed coupling reaction of Si-H bond in PMHS with vinyl in UA and amination reaction of catechol in dopamine (DA) with carboxyl on the surface of UA-co-PDMS which was synthesized by excessive Si-H bond and alkenyl polysiloxane (PMVS) were carried out. The results showed that the contact angle of UA-co-PMDS film by grafting DA on water and glycerin decreased from 107~, 110~to 54~, 69~, respectively, and the surface energy reached 55.05mJ/m2, which increased 4.7 times.