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Synthesis of Ni nanowires via a hydrazine reduction route in aqueous ethanol solutions assisted by external magnetic fields
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  • 分类:O614.813[理学—无机化学;理学—化学] TB383.1[一般工业技术—材料科学与工程]
  • 作者机构:National Key Laboratory of Nano/Micro Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of Ministry of Education, Institute of Micro and Nano Science and Technology, Shanghai Jiao Tong University
  • 相关基金:support of the National Basic Research Program of China(No.2006CB300406);Shanghai Science and Technology Grant(No:0752nm015);National Natural Science Foundation of China(No.50730008,20504021);Natural Science Foundation of Shanghai(No.09ZR1414800);Shanghai Applied Materials Collaborative Research Program(No:09520714400)
中文摘要:

One-dimensional Ni nanostructures were synthesized via a hydrazine reduction route under external magnetic fields. The mixture of de-ionized water and ethanol was used as the reaction solvent and hydrazine hydrate as reducing agents. The morphology and properties of Ni nanostructures were characterized by X-ray diffractometer(XRD), scanning electron microscopy(SEM), and vibrating sample magnetometer(VSM). It was found that the magnetic field strength, concentration of Ni ions,reaction time and temperature as well as p H values played key roles on formation, microstructures and magnetic properties of Ni nanowires. The optimal wires have diameter of ~200 nm and length up to ~200 μm. And their coercivity is ~260 Oe, which is much larger than the commercial Ni powders of 31 Oe. This work presents a simple, low-cost, environment-friendly and large-scale production approach to fabricate one-dimensional magnetic materials. The resulting materials may have potential applications in conductive filters, magnetic sensors and catalytic agents.

英文摘要:

One-dimensional Ni nanostructures were synthesized via a hydrazine reduction route under external magnetic fields. The mixture of de-ionized water and ethanol was used as the reaction solvent and hydrazine hydrate as reducing agents. The morphology and properties of Ni nanostructures were characterized by X-ray diffractometer (XRD), scanning electron microscopy (SEM), and vibrating sample magnetometer (VSM). It was found that the magnetic field strength, concentration of Ni ions, reaction time and temperature as well as pH values played key roles on formation, microstructures and magnetic properties of Ni nanowires. The optimal wires have diameter of similar to 200 nm and length up to similar to 200 mu m. And their coercivity is similar to 260 Oe, which is much larger than the commercial Ni powders of 31 Oe. This work presents a simple, low-cost, environment-friendly and large-scale production approach to fabricate one-dimensional magnetic materials. The resulting materials may have potential applications in conductive filters, magnetic sensors and catalytic agents.

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