采用直流反应磁控溅射方法,由氨气和氧气的混合气体在玻璃和单晶硅衬底上制备Al、N共掺Zn1-xMgxO薄膜。采用XRD、FE—SEM、Hall实验、UV—VIS透射谱以及EDS等方法对共掺Zn1-xMgxO薄膜的结晶性能、电学和光学性能进行研究。结果表明:薄膜有明显的C轴择优取向,玻璃衬底上制备的p-Zn0.9Mg0.1 O薄膜的电阻率为8.28Ω·m,空穴浓度和迁移率分别为1.09×10^19cm^-3和0.069cm^2/V·S。并且掺Mg的ZnO薄膜透射光谱表现出明显的蓝移。p-Zn0.9Mg01O/n-Si异质结的I-V特性曲线表现出明显的整流特性,可以确定制备的Al、N共掺Zn0.9Mg0.1O薄膜的导电类型是P型的。
The Al-N codoped Zn1-xMgxO thin films were deposited on glass and single-crystal Si substrates by DC reactive magnetron sputtering. The thin films possess a good crystallinity with c-axis orientation, confirmed by XRD patterns. Via Hall effect measurement, the result shows that the resistivity of the p-Zn0.9Mg0.10 thin film is 8.28 Ω·cm,the hole concentration and mobility are 1.09 × 10^19 cm^-3 and 0.069 cm^2/V's. The transmittance spectra reveal a distinct blue shift between Al-N codoped Zn1-xMgxO and undoped ZnO thin films. With good rectifying characteristics, and low current leakage under the bias voltage, the I-V characteristics of the p-Zn0.9Mg0.1O/n-Si heterojunction confirms the p-type conduction of the A1-N codoped Zn0.9Mg0.1O thin film.