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脉冲激光沉积法(PLD)生长Co掺杂ZnO薄膜及其磁学性能
  • ISSN号:1000-7032
  • 期刊名称:发光学报
  • 时间:0
  • 页码:203-208
  • 语言:中文
  • 分类:O472.5[理学—半导体物理;理学—物理]
  • 作者机构:[1]浙江大学硅材料国家重点实验室,浙江杭州310027, [2]杭州电子科技大学理学院材料物理研究所,浙江杭州310018
  • 相关基金:基金项目:国家“973”计划(2006CB604906);国家自然科学基金(50532060,50772099)资助项目
  • 相关项目:稳定优质的p型ZnO可控生长与同质ZnO-LED电致发光
中文摘要:

采用脉冲激光沉积(PLD)法在单晶Si(100)及石英衬底上生长Co掺杂ZnO薄膜,并且比较了不同生长条件下薄膜的性能。实验观察到了700℃、0.02Pa氧压气氛下生长的Co掺杂ZnO薄膜显示室温磁滞回线。采用XRD、SEM等手段对Co掺杂ZnO薄膜的晶体结构及微观形貌进行了分析,得到的ZnO薄膜具有高度的c轴择优取向,结构比较致密,表面平整度较高,并且没有发现Co的相关分相,初步表明Co有效地掺入了ZnO的晶格当中。霍尔测试表明Co掺杂ZnO薄膜样品保持了半导体的电学性能,电阻率为0.04Ω·cm左右。载流子浓度约为10^18/cm^3,迁移率都在18.7cm^2/V·s以上。实验结果表明材料保持了ZnO半导体的性能,并具有室温铁磁性。

英文摘要:

Diluted magnetic semiconductors ( DMS), in which some atoms of host semiconductors are randomly substituted by magnetic atoms, are regarded as key materials for spintronics because they have charge and spin degrees devices since its of freedom in a single substance. ZnO is a potential candidate for applications of spintronics possibility for room temperature ferromagnetism and its intrinsic excellent electrical properties. ZnO is also suitable for fabricating cartier controllable ferromagnetism because carrier-controlling techniques for ZnO have been well established. And among the methods used for deposition of thin films, PLD is effective and has the advantage that the ratios of the elemental components of the bulk and film are almost the same, even for chemically complex systems. In this paper, Zn0.95 Co0.05 O thin films were prepared by pulse laser deposition(PLD) on silicon(100) and quartz substrates. By optimizing the growth conditions, the Codoped ZnO thin films obtained at temperature of 700℃ and oxygen pressure of 0.02 Pa showed magnetism even at room temperature. The X-ray diffraction patterns suggested that the obtained films showed c axis orientation preference, and Co related phases such as Co2O3 didn't appear, simply indicating that Co ions had been successfully doped into ZnO crystal lattices. SEM images showed that the films have dense surfaces with small roughness. The obtained sample was measured to have a hole concentration of -10^18 cm^-3, a mobility of 18.7cm^2·V^-1·s^-1,and a resistivity of about 0.04Ω·cm, maintaining semieonduetivity. And the magnetization of the Co-doped ZnO film can be measured at 12K, even at room temperature.

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期刊信息
  • 《发光学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国物理学会发光分会 中国科学院长春光学精密机械与物理研究所
  • 主编:申德振
  • 地址:长春市东南湖大路3888号
  • 邮编:130033
  • 邮箱:fgxbt@126.com
  • 电话:0431-86176862
  • 国际标准刊号:ISSN:1000-7032
  • 国内统一刊号:ISSN:22-1116/O4
  • 邮发代号:12-312
  • 获奖情况:
  • 物理学类核心期刊,2000年获中国科学院优秀期刊二等奖,中国期刊方阵“双效”期刊
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  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:7320