欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
在微波辐射下,以无水碳酸钾为催化剂,经芳氧基苯并咪唑的aza-Michael加成反应合成了一系列2-芳氧甲基苯并咪唑-1-丙腈衍生物.经元素分析、IR、1 HNMR和13 CNMR对其进行了表征,用单晶X射线衍射测定了化合物4e的晶体结构.结果表明,化合物4e属三斜晶系,晶胞参数a=1.041 3（3）nm,b=1.592 7（4）nm,c=0.995 1（3）nm,α=90°,β=111.007（15）°,γ=90°,V=1.540 7（7）nm3,Z=4,F（000）=672.晶胞堆积发现化合物通过分子间氢键和π-π相互作用自组装成了一维链状超分子结构.
英文摘要：
A series of new 2-a Michael addition under micro ^13CNMR. The molecular str shows that the complex is inc ryloxymethylbenzimidazole-l-propionitrile derivatives are synthesized by azawave-irradiation and cKaracterized by elemental analysis, IR, ^1HNMR and ucture of 4e is determined by single crystal X-ray diffraction. The result luding in the Triclinie system, a=1.041 3（3） nm, b=1.592 7（4） nm, c= 0.995 1（3） nm, a=90°, β=111.007（15）°, γ=90°, V=1.540 7（7） nm^3, Z=4, F（000）=672. The cell packing diagram shows that the complex is self-assembled with l-dimensional supramolecular chain supported by H-bonds and π-π interactions.
同期刊论文项目
同项目期刊论文
Rationally designed anion-responsive-organogels: sensing F(-) via reversible color changes in gel-ge
A rapid selective colorimetric and ‘On–Off’ fluorimetric sensor for detecting Cu2+ ions in aqueous m
Synthesis of Copillar[5]arene by Co–oligomerization of Different Monomers and Its Application to Sup
A cationic water–soluble pillar[5]arene: synthesis and host–guest complexation with long linear acid
An easy prepared double naphthalene Schiff-base for highly selective sensing of cyanide via the dipo
A highly selective dual-channel chemosensor for mercury ions: utilization of the mechanism of intram
Rationally designed supramolecular organogel dual-channel sense F？ under gel–gel states via ion-cont
Selective fluorescent sensor for mercury(II) ion based on an easy to prepare double naphthalene Schi
A novel strategy for the design of smart supramolecular gels: controlling stimuli-response propertie
A reversible fluorescent chemosensor for Fe~(3+) and H_2PO_4~- with “on-off-on” switching in aqueous
Synthesis and Crystal Structures of a 1D Cu Coordination Polymer Based on Tetrakis[3-(carboxyphenyl)
A highly selective colorimetric sensor for Hg2+ based on a copper (II)complex of thiosemicarbazone i
A simple pincer-type chemosensor for reversible fluorescence turn–on detection of zinc ion at physio
Nitrophenylfuran–benzimidazole–based reversible alkaline fluorescence switch accurately controlled b
A ‘‘keto–enol tautomerization’’-based response mechanism: a novel approach to stimuli–responsive sup
Rewritable security display material and Cl？ sensor: Based on a bimetal competitive coordination con
A fluorescent and colorimetric chemosensor for dihydrogen phosphate ions based on 2-pyridine-1H-imid
A reversible and highly selective fluorescent probe for monitoring Hg2+ and iodide in aqueous soluti
Competitive coordination control of the AIE and micro states of supramolecular gel: an efficient app
Double metal ions competitively control the guest-sensing process: a facile approach to stimuli-resp
A Fluorescent Chemosensor for Dihydrogen Phosphate Ion Based on 2-[2-Hydroxy-4-(diethylamino) phenyl
Highly reversible “on–off–on” fluorescence switch and logic gate accurately controlled by pH based o
TICT–ICT state change mechanism based acetate fluorescent sensor act as an “Off–On–Off” switch and l
Copillar[5]arene–based supramolecular polymer gel: controlling stimuli–response properties through a
TICT–ICT state change mechanism based acetate fluorescent sensoract as an “Off–On–Off” switch and lo
Cadmium-induced supramolecular hydrogels: Reversible sol–gel transitions induced by EDTA and acid/ba
A highly selective dual-channel Hg2+ chemosensor based on an easy to prepare double naphthalene Schi
Highly selective fluorescent sensing for CN- in water: utilization of the supramolecular self-assemb
Mercapto thiadiazole-based sensor with colorimetric specific selectivity for AcO- in aqueous solutio
Cadmium-induced supramolecular hydrogels: Reversible sol–gel transitions inducedby EDTA and acid/bas
Multi-stimuli responsive metal-organic gel of benzimidazol-based ligands with lead nitrate and their
Colorimetric chemosensor and test kit for detection copper(II) cations in aqueous solution with spec
Selective Chemosensor of Fe3+ Based on Fluorescence Quenching by 2,2 '-Bisbenzimidazole Derivative i
A reversible fluorescent chemosensor for mercury ions based on 1H-imidazo[4,5-b]phenazine derivative
A naphtholic Schiff base for highly selective sensing of cyanide via different channels in aqueous s
A highly selective and sensitive chemosensor for instant detection cyanide via different channels in
Reaction-based Dual-Channel Ratiometric Chemosensor for Instant Detection Cyanide in Water with High
Syntheses, Crystal Structures and Properties of Three New Complex Constructed from 3,5-Dinitrobenzoi
A highly selective fluorescent chemosensor for iron ion based on 1H-imidazo [4,5-b] phenazine deriva
A silver-induced metal-organic gel based on biscarboxyl-functionalised benzimidazole derivative: sti
期刊信息
位置：