利用常规方法合成了一个Anderson型多酸化合物[(H2bbi)(CrMo6H7O24)]·4H2O,并通过元素分析和X-射线单晶衍射仪对其进行结构表征.该化合物属于三斜晶系,P-1空间群,a=7.8223 (7)A,b=8.9003(9)A,c=12.1326(10)A,α=86.193(7)°,β=86.951(7)°,γ=76.752(8)°,V=819.76(13)A3,Z=1.多酸阴离子、bbi配体和游离的水分子之间通过氢键作用形成三维超分子网状结构.
A new compound [ (H2bbi) (CrMo6H7024)] · 4H20 was synthesized and characterized by elemental analysis and single - crystal X - ray diffraction. The title compound crystallizes was in triclinic space, group P - 1 with a=7.8223 (7)A,b=8.9003(9)A,c=12.1326(10)A,α=86.193(7)°,β=86.951(7)°,γ=76.752(8)°,V=819.76(13)A3,Z=1. and Z = 1. The anions, bbi ligands and free water molecules through hydrogen bonds formed the three - dimensional supramolecular network.