基于氢键取代作用,氟离子可以降低巯基乙胺-CdTe量子点之间的团聚,提高量子点的分散性,使量子点的水合粒径随着氟离子浓度的增加而逐渐减小.基于此,本文发展了一种基于动态光散射(DLS)技术检测氟离子的方法,其检出限为20nmoL/L,与荧光方法和传统的氟离子选择性电极相比,其检出限降低了约2个数量级.
The cystea mine-capped CdTe quantum dots (QDs) undergo spontaneous self-aggregation via NH--N hydrogen bonds. In the presence of F-, the aggregates disassembled due to the substitution of NH--F hydrogen bonds for NH--N hydrogen bonds. Thus, the hydrodynamic size of the QDs aggregates was de- creased gradually as the concentration of F- increased. Here, a one-step sensitive method using dynamic light scattering(DLS) was introduced for directly detection of F-. The detection limit of this method was ca. 20 nmol/L. It was ca. 2 orders of magnitude lower than that of fluorscence methods and F- selective electrode, as reported previously.