采用真空冷冻干燥技术、微波消解方法处理牦牛乳样品后,直接用电感耦合等离子质谱仪(ICP-MS)测定了牦牛乳中的14种微量元素。外标法绘制标准曲线,相对标准偏差1.80%~4.50%,加标回收率95.61%~102.90%。分析结果表明牦牛乳中含有人体中存在的多种微量元素,其干物质中的微量元素含量平均值分别为Cu 0.340μg/g,Zn 50.65μg/g,Fe 16.12μg/g,Mn 0.843μg/g,Mo 0.170μg/g,Co 0.023μg/g,Ni 0.522μg/g,Ti 0.001μg/g,V 0.105μg/g,Li 0.056μg/g,Be 0.003μg/g,Bi 0.029μg/g,Pb 0.305μg/g,Cd 0.014μg/g。
Yak milk samples were freeze dried in a vacuum chamber and digested using microwave, and the digestion solution was directly injected into inductively coupled plasma-mass spectrometry (ICP-MS) for quantitative determination of trace elements by external standard method. The relative standard deviations of precision of this method were between 1.80% and 4.50%, and the spiked recoveries ranged from 95.61% to 102.90%. Yak milk contained a variety of trace elements which exist in the human body, and the average contents of the trace elements in yak milk were (calculated on dry matter basis): Cu 0.340, Zn 50.6, Fe 16.12, Mn 0.843, Mo 0.170, Co 0.023, Ni 0.522, Ti 0.001, V 0.105, Li 0.056, Be 0.003, Bi 0.029, Pb 0.305, and Cd 0.014 μ g/g, respectively.