使用绿色磷光材料GIrl作为掺杂剂,制备了基于CBP材料的一系列绿色有机电致发光器件(OLED)。其器件的结构为ITO/M003(50nm)/NPB(40nm)/TCTA(10nm)/CPB:GIrl(30nm,x%)/BCP(10nm)/Alq3(20nm)/LiF(1nm)/AI(100nm),其中x%为发光层客体掺杂质量分数。对7种不同的掺杂剂质量分数进行了比较,研究了它们的电致发光(EL)特性。结果显示,对发光面积为2.72cm0的器件,GIrl的最佳掺杂比为14%,器件的起亮电压为3.5V,器件的最大电流效率26.2cd/A,其相应的EL主峰位于524nm,色坐标为(0.34,0.61),得到了发光性能稳定的绿色0LED。
Abstract.Green phosphorescent organic light emitting devices (OLEDs) were fabricated by doping green phosphorescent dye Girl and with the host material CBP as the emitting layer. The structure of the de- vices is ITO/MoO3 (50 nm)/NPB(40 nm)/TCTA(10 nm)/CPB.GIrl(30 nm,x%)/BCP(10 nm)/Alq3 (20 nrn)/LiF (1 nm)/Al(100 nm) ,in which x% is the doping mass fraction of Girl. Comparing 7 kinds of different dopant mass fractions, the luminescence characteristics of the devices are investigated. It is found that the best dopant mass fraction is 14% for the device with 2.72 cm2 light-emitting area, the turn-on voltage of this device is 3.5 V and the current efficiency is 26.2 cd/A. The electroluminescent (EL) spectra show a prominent peak at 524 nm and the color coordinate is (0. 34,0. 61). We have ob- tained a green organic electroluminescent device with stable luminescent properties.