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生物淋滤直接浸出废旧电池中有毒重金属的实验研究
  • ISSN号:0254-6108
  • 期刊名称:《环境化学》
  • 时间:0
  • 分类:X172[环境科学与工程—环境科学]
  • 作者机构:[1]北京理工大学化工与环境学院,北京100081
  • 相关基金:国家“973”计划资助(2002CB211800).
中文摘要:

考察了生物淋滤对5种电池中重金属的溶出效果,比较了化学浸提和生物淋滤对三种电池中重金属的溶出效率,研究了起始pH值对生物淋滤溶出电池中重金属的影响模式.结果表明,生物淋滤对5种电池中6种离子的平均浸出浓度超过350mg·l^-1,锌锰电池(华太)锰浸出浓度、锌锰电池(南孚)锌浸出浓度和镍氢电池的镍浸出浓度分别达524mg·l^-1,600mg·l^-1和750mg·l^-1;而化学浸提对3种电池中5种金属的溶出浓度均不超过10mg·l^-1.起始pH值对生物淋滤电池的离子浸出效率影响巨大.起始pH值愈低,离子浸出浓度愈高.在起始pH值为2.0的生物淋滤体系中,镍镉电池的镍镉浸出平均浓度为350mg·l^-1,而起始pH值为4.0和5.5的淋滤体系中,在整个反应时间内镍镉几乎未能检出.

英文摘要:

Bioleaching is attempted to release heavy metals from the wasted batteries. The bioleaching efficiency of different heavy metals from 5 kinds of batteries was investigated ; The comparison in release efficiency between bioleaching and chemical extraction was carried out; The influence of initial pH on the bioleaching efficiency was studied. The results showed that the average concentration of 6 kinds of heavy metals released from 5 kinds of batteries by bioleaching was over 350 mg·l^-1, the released concentration of Mn from the Zn-Mn dry battery (huatai), Zn from the Zn-Mn dry battery(nanfu) and Ni from the Ni-MH battery reached 524 mg·l^-1, 600 mg·l^-1 and 750 mg·l^-1 respectively, while the released concentration by chemical extraction is lower than 10 mg·l^-1. Initial pH greatly affected the bioleaching efficiency of heavy metals. The average bioleaching concentration of Ni and Cd from the Cd-Ni battery was 350 mg·l^-1 at initial pH 2. 0, while both Ni and Cd cannot be detected at initial pH 4. 0 or higher. The results demonstrated that bioleaching has great potential in releasing heavy metals from wasted batteries.

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期刊信息
  • 《环境化学》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:郭良宏
  • 地址:北京2871信箱
  • 邮编:100085
  • 邮箱:hjhx@rcees.ac.cn
  • 电话:010-62923569
  • 国际标准刊号:ISSN:0254-6108
  • 国内统一刊号:ISSN:11-1844/X
  • 邮发代号:82-394
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:27127