比较了四环素(TC)、土霉素(OTC)和金霉素(CTC)这3种四环素类物质在不同pH条件下的光降解和光催化降解速率。结果表明,在紫外光(uV)作用下3种四环素类物质的降解速率由高到低依次为OTC、CTC和TC,而在UV—TiO2光催化体系下,pH值为3.0~7.0时3者的降解速率无明显差异;碱性条件有利于TC、OTC和CTC的光降解和光催化降解,且降解过程中有NH4+生成。
Comparisons were made between tetracycline ( TC ) , oxytetracycline ( 0TC ) and chlortetracycline ( CTC ) in photodegradation and photocatalytic degradation in solutions different in pH. Results show that under UV light, they fol- lowed the order of OTC 〉 CTC 〉 TC in photodegradation rate. However, under UV - Ti02 photocatalysis, they demon- strated little difference in solutions with pH in the range of 3.0 - 7.0. Increasing solution pH facilitated both the photodeg- radation and photocatalysis degradation of TCs, and NH4 ions were generated during these processes.