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利用P-MBE制备高质量MgxZn1-xO的结构和光学特性
  • ISSN号:1000-7032
  • 期刊名称:《发光学报》
  • 时间:0
  • 分类:O482.31[理学—固体物理;理学—物理]
  • 作者机构:[1]中国科学院长春光学精密机械与物理研究所激发态物理重点实验室,吉林长春130033
  • 相关基金:国家自然科学基金重点基金(60336020,50532050);"973"计划(2006CB60406)资助项目
中文摘要:

利用等离子体辅助分子束外延(P-MBE)的方法,在c平面的蓝宝石衬底上制备了高质量的MgxZn1-xO合金薄膜。通过改变Mg源的温度,得到了不同Mg组份的MgxZn1-xO合金薄膜;通过引入ZnO的低温缓冲层,有效地提高了MgxZn1-xO合金薄膜的结晶质量。随着Mg组份的增加,MgxZn1-xO的X射线衍射的(002)衍射峰逐渐向大角度方向移动。对样品进行光致发光(PL)谱的测量,在室温下观察到了较强的紫外发光。随Mg浓度的增加,紫外发光峰向高能侧移动,并且发光峰逐渐展宽。通过对x=0.15的样品进行变温光谱的测量研究了紫外发光峰起因,得到了MgxZn1-xO的发光是来自于自由激子的发光。自由激子束缚能为54meV。

英文摘要:

ZnO is a wide band-gap semiconductor with good electrical and optical properties. ZnO has higher exciton binding energy of 59 meV at room temperature, leading to a lower threshold, and is favorable for efficient operation of optical devices. Short wavelength devices based on ZnO have become even more interesting. On the other hand, band gap devices based on ZnO/ZnMgO superlattices or quantum wells can confine both excitons and photons in the low dimensions, making the stimulated exciton-related emission process more efficient. Therefore, keeping focus on the MgxZn1-xO films for purpose of exploring its potential applications in ultraviolet optoelectronics is more and more important. High quality MgxZn1-xO alloy films have been grown by plasma-assisted molecular beam epitaxy on c-sapphire (c-Al2O3 ) substrate. The growth temperature was 800 ℃ , the temperature of the zinc source is fixed at 245 ℃, and the flow rate of oxygen is 0.8 seem. The MgxZn1-xO films were obtained with different Mg contents by changing the temperature of the Mg source. The quality of the MgxZn1-xO films was improved by growing ZnO buffer layers at low temperature. Their crystal structures are characterized by X-ray diffraction spectroscopy (XRD). The XRD patterns indicate all the MgxZn1-xO films with the (002) preference orientation of hexagonal wurtzite structure. When x value is varied from 0 to 0. 15, the (002) diffraction peak of MgxZn1-xO shifts to the large angle side with increasing Mg contents, and the full wide at half maximum (FWHM) of the diffraction peak is widen with increasing Mg contents. The lattice constant of c-axis decreases from 0. 520 5 nm to 0.518 9 nm as the Mg content increased from 0 to 0.15. The FWHM is only 0. 145° for the Mg0.15Zn0.85O film, which exhibited the high quality of the MgxZn1-xO films. The intense ultraviolet emission was shown in photoluminescence spectra at room temperature, which shifts from 3.29 eV (x = 0) to 3.54 eV(x =0.15 ) with increasing x values. The bandgap

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期刊信息
  • 《发光学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国物理学会发光分会 中国科学院长春光学精密机械与物理研究所
  • 主编:申德振
  • 地址:长春市东南湖大路3888号
  • 邮编:130033
  • 邮箱:fgxbt@126.com
  • 电话:0431-86176862
  • 国际标准刊号:ISSN:1000-7032
  • 国内统一刊号:ISSN:22-1116/O4
  • 邮发代号:12-312
  • 获奖情况:
  • 物理学类核心期刊,2000年获中国科学院优秀期刊二等奖,中国期刊方阵“双效”期刊
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  • 被引量:7320