本文通过批淋滤实验研究了某电厂2号炉三个静电除尘器下粉煤灰中Cd、Cr、Pb、V的淋滤特性。淋滤液选择pH=4的HCI和pH=10的NaOH溶液,液固比为4:1;批淋滤选取从15分钟到7天的14个时间进行。实验结果显示,在实验条件下,Cr在酸性条件下淋出滤较高,而Pb在碱性条件下淋出滤较高;其中Cr随着淋滤时间的增加,淋出滤有显著增加,且三种粉煤灰中淋出滤大小为LCr3〉LCr2〉LCr1。
Batch leaching tests have been performed on fly ashes collected from three electrostatic precipitators(ESP) of 2# furnace in a coal-fired power plant in order to study the leaching characteristics of Cd, Cr , Pb, V in fly ashes. Leaching solutions are chosen with HCl solution of initial pH=4 and NaOH solution of pH=10, liquid/solid=4:1, forteen leaching times are chosen, different from 15 minutes to 7 days. The results show that under the experimental conditions, Cr has a relatively high leachability in acid leaching solution, while Pb has a high leachability in alkaline solution. Besides, with the accumulating of leaching time, the leachability of Cr has obviously increased, and the leachability in three coal ashes shows a tendency as follows: LCr3 〉 LCr2 :〉 LCr1.