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先驱体法制备非晶态SiCNO材料
  • ISSN号：1673-2812
  • 期刊名称：《材料科学与工程学报》
  • 时间：0
  • 分类：TQ174.1[化学工程—陶瓷工业;化学工程—硅酸盐工业]
  • 作者机构：哈尔滨工业大学, 哈尔滨东安发动机(集团)有限公司
  • 相关基金：国家自然基金资助项目(NSFC NO.51021002、NSFC NO.5107241和50902031)
作者： 孙振淋, 张茜, 周玉, 贾德昌
关键词： 无定形, SiCNO, 先驱体, 溶剂热路线
中文摘要：

以甲基乙烯基二氯硅烷、乙烯基三氯硅烷、氨基甲酸铵和环己烷作为原料,通过溶剂热合成路线制备出SiCNO陶瓷的液态先驱体。先驱体经1100℃热解后,转变为非晶态SiCNO材料。FT-IR红外分析显示先驱体中含有异氰酸酯官能团。非晶态SiCNO具有良好的高温热稳定性,在1500℃时仍保持无定形状态,1600℃以上时基体中析出Si2N2O和少量的β-SiC相。

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期刊信息
  • 《材料科学与工程学报》
  • 北大核心期刊（2011版）
  • 主管单位:国家教育部
  • 主办单位:浙江大学
  • 主编：叶志镇
  • 地址：浙江杭州浙大路38号浙江大学材料系
  • 邮编：310027
  • 邮箱：jmse@ema.zju.edu.cn
  • 电话：0571-87951403
  • 国际标准刊号：ISSN：1673-2812
  • 国内统一刊号：ISSN：33-1307/T
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,中国中国科技核心期刊,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）
  • 被引量:9446