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Cr含量对(TiBw+TiCp)/(Ti-4.0Fe-7.3Mo-xCr)复合材料组织及性能的影响
  • ISSN号:0258-7076
  • 期刊名称:《稀有金属》
  • 时间:0
  • 分类:TB331[一般工业技术—材料科学与工程]
  • 作者机构:[1]哈尔滨工业大学材料科学与工程学院,黑龙江哈尔滨150001, [2]中国人民解放军第二炮兵驻哈尔滨地区军事代表室,黑龙江哈尔滨150001
  • 相关基金:中央高校基本科研业务费专项资金(HIT.KLOF.2010042),国家自然科学基金创新研究群体(51021002)资助项目
中文摘要:

钛合金因其优异的强韧性是具有广泛应用背景的轻质材料,但其硬度较低导致耐磨性较差,限制了其作为结构部件的应用。利用Cr3C2,B4C和石墨粉体之间的原位反应,制备了增强相体积分数为10%,TiC和TiB摩尔比1:1的(TiBw+TiCp)/(Ti4.0Fe-7.3Mo-xCr)系钛合金基复合材料。混合粉料采用热压烧结方法在20MPa压力,氩气气氛保护,1300℃条件下保温1h进行制备。并对复合材料的微观组织结构和力学性能进行了研究。研究表明,通过控制Cr3C2,B4C和C的含量配比,改变以Cr3C2引入的cr含量对基体和增强相均有影响。复合材料基体由a—Ti和β-Ti两相组成,随Cr3C2引入的cr含量的增加,β-Ti的含量增加。并且当Cr3C2形式引入的Cr含量由2.2%增加到5.2%时,复合材料的强度得到显著提高,最高可达到908.7MPa,但其杨氏模量从170GPa下降到150GPa,而复合材料的洛氏硬度HRC稳定保持在55,大大高于基体合金。并且CraC2的引入也影响着复合材料中原位合成的TiBw与TiCp增强相的分布位置和形态。随由Cr3C2的引入Cr含量增加,TiB晶须的长径比提高,TiC颗粒的粒度细化,对复合材料的强度和韧性起到强化作用。

英文摘要:

Titanium alloys had a wide application as their good toughness and strength, but these alloys had relatively low abrasion resistance as the low hardness which limited their application as structure parts. The titanium matrix composites, 10% (TiBw + TiCp)/ (Ti-4.0Fe-7.3Mo-xCr) composites with TiB: TiC = 1: 1, were prepared by in situ reaction between B4C, C, Cr3 C2 and titanium pow- ders. The mixtures were hot pressed at 1300℃, under a pressure of 20 MPa for i h in Ar atmosphere. Microstructure and mechanical properties of the composites were investigated. The results showed that" by changing the proportions of Cr3 C2, B4 C, and C, the content of Cr from Cr3 C2 could affect both the matrix and reinforcing phase. The composite was comprised of the c~-Ti and ~-Ti phase, and the content of 13-Ti phase increased with the content of Cr from Cr3 C2 increased by in situ reaction. With the increase of Cr content from Cr3C2 varied from 2.2% to 5.2%, the strength increased significantly, up to 908.7 MPa, while the Young's modulus decreased from 170 to 150 GPa, but the hardness (HRC) of the TMCs was much higher than that of the matrix alloy and remained steadily at 55. Ad- ditionally, the introduction of Cr3C2 could also influence the distribution and morphology of in situ formed TiBw and TiCp reinforce- ments. With the increase of Cr content from the Cr3C2, the aspect ratio of the TiBw rose, and the granularity of the TiCp declined which enhanced the strength and toughness of the composites.

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期刊信息
  • 《稀有金属》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:北京有色金属研究总院
  • 主编:屠海令
  • 地址:北京新街口外大街2号
  • 邮编:100088
  • 邮箱:xxsf@grinm.com
  • 电话:010-82241917 62014832
  • 国际标准刊号:ISSN:0258-7076
  • 国内统一刊号:ISSN:11-2111/TF
  • 邮发代号:82-167
  • 获奖情况:
  • 中文核心期刊,冶金工业类核心期刊,中国科技论文统计源期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:13688