运用等温热重技术,以C02为气化剂,在常压和1000℃~1300℃温度范围内,考察了义马煤焦的气化反应性.结果表明,随着气化温度的提高,义马煤焦的反应性和反应速度呈现出增加的趋势,但在灰熔融温度附近出现不同的情况.碳还原率为50%时,1000℃~1100℃和1100℃~1300℃的气化反应活化能分别为140.97kJ/mol与20.84kJ/mol.
The CO2 gasification reactivity of Yima coal char were investigated by an isothermal thermo-gravimetric analysis at ambient pressure and at temperatures from 1 000℃ to 1 400℃. The results showed that general gasification reactivity and reaction of chars increased with gasification temperature, but some different phenomenon appeared near coal ash fusion point. When conversion was 50%, the average apparent activation energies of chars respectively were 224.03 kJ/mol and 31.47 kJ/mol at 1 000 ℃-1 100℃ and 1 100℃-1 300℃. KEY WORDS Yima coal char, isothermal thermo-gravimetric analysis, gasification reactivity