对Pb(Ni1/3Sb2/3)-PbZrO3-PbTiO3陶瓷烧结和压电性能的研究表明:当含有48mol%PbTiO3和少于10mol%Pb(Ni1/3Sb2/3)的粉体在850℃下煅烧2h,得到单一钙钛矿结构,但是如果Pb(Ni1/3Sb2/3)组成在12mol%~14mol%之间时,则三方相和四方相共存。所以材料的准同相界在Pb(Ni1/3Sb2/3)=12mol%,PbZrO3=40mol%,PbTiO3=48mol%。当该组分在1260℃至1280℃烧结时得到的烧结物密度最大为7.8g/cm^3。扫描电镜结果表明在1280℃时材料烧结气孔率最小。当处于准同相界的组分在1280℃烧结时,材料的机电耦合系数酶和机械品质因数Qm分别达到最大值0.488和最小值292.5。
The sintering and piezoelectric properties of Pb(Ni1/3Sb2/3)O3-PbZrO3-PbTiO3 ceramics were investigated. When the powder contained 48 mol% PbTiO3 and less than 10 mol% Pb(Ni1/3Sb2/3)O3 followed by calcination at 850℃ for 2 h, the perovskite structure was obtained only; if the Pb(Ni1/3Sb2/3)O3 content was between 12 mol% and 14 mol%, both tetragonal and rhombohedral phases were obtained. The composition of the morphotropic phase boundary (MPB) in the Pb(Ni1/3Sb2/3)O3-PbZrO3-PbTiO3 system is Pb(Ni1/3Sb2/3)O3 =12 mol%, PbZrO3 =40 mol% and PbTiO3 =48 mol%. As the compact with composition at the MPB was sintered at 1260℃-1280℃ for 2 h, the maximum density of the sintered compact was 7.8 g/cm^3. The SEM micrographs indicated that the minimum porosity was reached upon sintering at 1280℃. When the compact with composition at MPB was sintered at 1280℃ for 2 h, the planar coupling coefficient (Kp) and mechanical quality coefficient (Qm) approached the maximum (0.488) and minimum values (292.5)