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灌河口海域沉积物中有机氯农药的空间分布、来源解析与风险评估
  • ISSN号:1007-6336
  • 期刊名称:《海洋环境科学》
  • 时间:0
  • 分类:P736[天文地球—海洋地质;天文地球—海洋科学]
  • 作者机构:[1]河海大学环境学院,江苏南京210098, [2]连云港市环境监测中心站,江苏连云港222001, [3]南京大学环境学院,江苏南京210046, [4]江苏省交通规划设计院股份有限公司,江苏南京210005
  • 相关基金:国家自然科学基金青年科学基金项目(40906054); 河口海岸学国家重点实验室开放基金资助项目(SKLEC-KF201208); 江苏省环保科技项目(2010043); 连云港市科技发展计划项目(SH1113);致谢:感谢南丹麦大学生物学院、奥胡斯大学生物信息学院的胡芬娟博士对本文摘要的修改,连云港市环境监测中心站李海燕等高级工程师在仪器分析过程中大力支持.
中文摘要:

2011年4月通过GC定量检测和210Pb测年对灌河口海域表层和柱状沉积物中OCPs(Organochlorine Pesticides)的空间分布、来源解析进行了研究。结果表明:灌河口海域表层沉积物中OCPs的浓度在nd~58.3×10-9(干重)之间,河口海域O,P'-DDT浓度明显高于潮间带和入海河段,3个区域浓度排序为:潮间带〉河口海域〉入海河段。DDTs和HCHs浓度均处于国内中等水平。柱状沉积物中OCPs浓度在(2.0~850.0)×10^-9之间、平均值210.0×10^-9,90年代初期OCPs浓度有所下降,2000年后又在波动中升高。来源解析及柱状样中OCPs浓度变化、转化情况均表明该海域沉积物有新的DDTs源输入。参照加拿大颁布的沉积物质量标准对灌河口沉积物进行风险评估,结果表明灌河口海域以DDT和DDD为主的毒性已处于频繁效应,需深入开展沉积物的环境风险评估研究,确认开展OCPs底质修复方案及区域。

英文摘要:

In this study, OCPs (Organochlorine Pesticides) in surface and column sediments from Guanhe Estuary (taken in April,2011 ) were analyzed by GC-ECD and 210Pb methods. The results showed that OCPs concentrations in surface sediments ranged from nd (Not Detected) to 58.3 × 10^-9( dry weight), and the concentrations range among three sampled regions are, from highest to the lowest, intertidal zone, estuary area and Guanhe River. However, concen- trations of O, P' -DDT were highest in the sediment from estuary area, compare to those from interidal zone or Guanhe River. Based on the studies in other areas in China, DDTs and HCHs concentrations around Guanhe estuary were aver- age. OCPs concentrations in column sediments ranged from 2.0 × 10^ -9 to 850.0 × 10^ -9 ,with an average of 210.0× 10^-9, and the results also indicated that the OCPs were relatively low in 1990s and increased in 2000. These results were validated by the studies around the area,that there were new inputs of DDTs sources in this region during the stucly period. Meanwhile, the ecological risks were also evaluated according to Sediment Quality Guidelines (SQCs) applied in Canada. According to SQCs,the adverse effects of OCPs in this area mainly originated from contaminationsof DDD and DDT,which could occur frequently. The study suggested that more research on risk assessment of OCPs need to be conducted in this area, and feasible solutions to restore sediment environments need to be formulated for Guanhe estuary.

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期刊信息
  • 《海洋环境科学》
  • 北大核心期刊(2011版)
  • 主管单位:国家海洋局
  • 主办单位:国家海洋局海洋环境保护研究所 国家海洋环境监测中心 中国海洋环境科学学会
  • 主编:关道明
  • 地址:大连市303信箱(沙河口区凌河街42号)
  • 邮编:116023
  • 邮箱:hyhjkx@vip.126.com
  • 电话:0411-84783126
  • 国际标准刊号:ISSN:1007-6336
  • 国内统一刊号:ISSN:21-1168/X
  • 邮发代号:
  • 获奖情况:
  • 第二届全国优秀科技期刊三等奖,首届全国环境期刊评比一等奖,2001、2002年度大连市优秀期刊,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),美国剑桥科学文摘,英国动物学记录,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:13001