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中文摘要：
将质量比为1：4的TiCl4和NaN。放入不锈钢反应釜内，以二甲苯为溶剂，填充率为60％，用溶剂热方法，在温度340℃，保温24h，制得粉体。粉体分别经二甲苯，无水乙醇、蒸馏水洗涤，105℃干燥和直接经700℃煅烧2h，XRD测试表明：制备出的氮化钛粉体为纳米立方相粉体，晶格常数a=0．4241nm，平均粒径为11．04nm，700℃煅烧后全部转化为TiO2和Ti的混合物；IR测试表明在619cm^-1的吸收峰归属为Ti—N键，表面吸附了一些有机溶剂，有C=C弯曲振动峰；SEM测试表明其晶粒有立方状、圆粒状，长柱状和内部有中孔的圆环状晶粒，表面存在毛绒状的细小晶须，形成网状包裹在晶粒表面。
英文摘要：
TiN nano-powders were synthesized in the stainless steel reaction kettle via solvothermal process at 340℃ for 24h, with xylene as the solvent and the filling ratio of 60% and m （TICl4） ： m （NAN3） = 1： 4. The synthesized powders were respectively directly dried, were washed by xylene, anhydrous alcohol and distilled water and then dried at 105 ℃ and were washed by xylene, anhydrous alcohol and distilled water and then calcined at 700 ℃ for 2h. XRD analysis indicate that the prepared TiN3 powders were nano-scale cubic-phase powders, with crystal lattice constant a = 0.4241 nm and average grain size of 11.04 nm. After calcination, the fabricated powders were detected as TiO2 and Ti. IR test revealed that the absorption peak at 619 cm^-1 was detected as Ti-N bond vibration, while the C=C bending vibration resulted from the organic solvent absorption on the surface of the powders was also found. SEM images showed that the micro-morphology of the prepared powders were diversiform, such as cubic grain, round grain, long column and the ring with a center hole inside. On their surfaces there were some tiny crystal whiskers presenting network to coat the crystal surface.
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