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自组装制备二氧化铪图案化薄膜
  • 期刊名称:无机化学学报. 2009, 25(10): 1853- 1857
  • 时间:0
  • 分类:TB43[一般工业技术] TQ134.13[化学工程—无机化工]
  • 作者机构:[1]陕西科技大学教育部轻化工助剂化学与技术重点实验室,西安710021, [2]河南大学法学院,开封475001
  • 相关基金:国家自然科学基金项目(No.50672055,50872077),国家科技支撑计划项目(No.2006BAF02A28),陕西科技大学研究生创新基金项目资助.
  • 相关项目:基于液相反应自组装制备透明柔性功能陶瓷薄膜及其生长机理的研究
中文摘要:

采用短波紫外光(UV)在十八烷基三氯硅烷(OTS)自组装单分子层刻蚀不同的微型图案,利用液相自组装技术在OTS模板表面沉积HfO2图案化薄膜。通过XRD、AFM、SEM、EDS等测试手段对OTS膜和HfO2薄膜进行表征,结果表明:以OTS为模板利用液相自组装技术成功制备出边缘轮廓清晰、粗糙度较小、条纹宽度为10μm的立方晶型的HfO2图案化薄膜。

英文摘要:

Different kinds of micro-patterns were created within octadecyltrichlorosilane (OTS) self-assembled monolayers utilizing UV lithography. The HfO2 pattern films have been formed on silanol SAMs by the liquid-phase deposition (LPD) method. The crystal phase composition, microstructure and topography of the as-prepared films were characterized by various techniques, including X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), and energy disperse spectroscopy (EDS). The results indicate that the HfO2 pattern films were successfully prepared by the self-assembled monolayers, and the thin films had cubic pattern microstructure of HfO2, 10 μm deposited lines width and small line edge roughness.

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