采用了溶胶-凝胶工艺在普通的玻璃载玻片上成功地制备出具有c轴择优取向性、高的可见光透光率、平整均匀的氧化锌薄膜。通过XRD、AFM以及UV光谱仪等分析,其结果表明:所制备的氧化锌薄膜具有纤锌矿型结构,表面均匀致密,薄膜晶粒尺寸大约在40~90nm,溶胶浓度增大时,其晶粒大小呈增大的趋势。随着涂膜层数的增加,薄膜的(002)方向的取向度增加。薄膜在可见光区的光透过率〉85%,在近紫外光波段透射率急剧减小,对应的禁带宽度为3.34eV。
The ZnO thin films are prepared on glass sheets by sol-gel technology, which are characterized by X-ray diffraction, atomic force microscopy and ultra-violet spectrum. The results indicate that the thin films are c-orientation, highly visible transmittance, homogeneous and dense surface with the crystalline structure of hexagonal wurtizite, the crystalline dimension of 40~90 nm. The crystal size increases with the increasing sol concentration, and the films are highly oriented in (002) direction as the growing of the film layers. The transmittance has a sharp fundamental absorption edge in UV region, the optical band gap is evaluate to be around 3.34 eV.