采用溶胶-凝胶法在硅(100)和玻璃衬底上制备了掺铝氧化锌(ZnO:Al)薄膜.当掺Al^3+浓度小于或等于15%时,得到的薄膜均为单一c轴取向.c轴晶格常数随掺Al^3+浓度的增加逐渐减小,当掺Al^3+浓度增至15%时,薄膜c轴晶格常数值减小约0.56%.薄膜的光学带隙随掺Al^3+浓度的增加而增大,掺Al3+20%的薄膜光学带隙达到3.99eV.O1s结合能随掺Al^3+浓度的增加而增大.
ZnO:Al thin films were deposited onto silicon (100) and glass substrates by sol-gel process. The Aldoped ZnO thin films with doping level below 15% showed only c-axis orientation. The c axis constant decreased with in creasing Al content, and the c-axis constant of ZnO:Al thin films with Al content of 15% decreased by about 0.56% compared with that of ZnO crystal. The optical band-gap showed evidently blueshift with increasing the Al^3+ concentration. For the sample doped with 20% Al^3+ content, the optical band-gap energy reached 3.99 eV. The binding energy of Ols increased with increasing Al content.