采用Sol-gel法使用旋转涂覆技术在Si(100)基片上生长了ZnO:Cd薄膜.XRD结果表明:ZnO:Cd薄膜具有与ZnO一样的六角纤锌矿结构,随热处理温度的升高,(002)衍射峰强度逐增,FWHM减小,并沿c轴择优取向生长;透射光谱实验表明:以石英为基底,适度掺镉可降低薄膜的禁带宽度Eg,特别是在800℃、8%Cd条件下,Eg=2.80eV,与纯ZnO的禁带宽度3.30eV相比,明显降低了光学禁带;光致发光谱(PL)实验表明:在吸收边附近均有较强的紫外发射峰,且随热处理温度升高呈规律的变化;电阻率测定表明:掺镉使薄膜导电性增强.
ZnO : Cd films are prepared on Si(100) substrates by the Sol-gel process using a spinning-technical. The films show a hexagonal wurtzite structure and C-axis orientation as observed by XRD. With the increase of heat-treating temperature, the intensity of diffraction peak increases and FWHM reduces. Optical transmittance spectra of ZnO : Cd films on quartz substrates indicate that bandgap of the film at 8 at%Cd under 800℃ annealing temperature is 2. 80eV. The bandgap is apparently narrower than that of ZnO bulk crystal(3. 30eV). The PL spectra show that all ZnO: CA thin films emit strong UV photoluminescence at room temperature and the emission band turns regular change with the heat-treating temperature increasing. Surface resistance shows that the CA-doped way makes the electric property of ZnO thin films improved.