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中文摘要：
以联萘二酚骨架的手性磷酸催化吲哚苄基醇和3-吲哚丙烯酸酯发生环加成反应，产生三个连续的手性中心.当使用3，3＇-位被α-萘取代的联萘二酚骨架手性磷酸为催化剂时，反应的效果最佳，产率最高达91%以上，非对映选择性为9∶1-20∶1，对映选择性为62%-92%.
英文摘要：
The cycloaddition reaction of a suitably substituted indolyl benzylic alcohol with an ethyl 3-indoleacrylate catalyzed by phos-phoric acids derived from （S）-BINOL was described. When the chiral phosphoric acid bearing α-naphthyl at 3,3＇-positions of the binaphthyl was used as a catalyst, pyrrolo[1,2-a]indole derivatives with three contiguous stereocenters were obtained in high yield up to 91%, with good to high diastereoselectivity （9/1-20/1 dr） and enantioselectivity （62%-92% ee for the major dia-stereoisomer）.
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