以物质的量的比为1:1的Ri(NO3)3·5H2O和Fe(NO3)3·9H2O为反应原料,以NaOH为矿化剂,利用水热法在Ti基板上成功制备出一维Bi2Fe4O9纳米棒阵列。对该纳米棒阵列分别进行XRD、FE-SEM、HR-TEM和UV—Vis测试,得到Bi2Fe4O9纳米棒的直径为100nm,长度为3-4μm,并表现出良好的光吸收性能,禁带宽度约为1.9eV,对甲基紫溶液的光降解率达到86%,其活性明显高于市售P25(TiO2)。该纳米棒阵列的生长方式完全遵循奥斯瓦尔德熟化(0stwald riening)单晶生长机理。
One-Dimensional Bi2Fe4O9 nanorod arrays on Ti substrates were synthesized with Fe(NO3)3·9H2O and Bi(NO3)3· 5H2O (molar ratio 1:1) by the hydrothermal method, using NaOH as the pH value adjuster and mineralizer. The nanorod arrays were characterized with X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), high-resolution TEM (HRTEM), Ultraviolet visible absorption spectroscopy (UV-Vis). The nanorods are 100 nm in diameter and 3-4 μm in length, and show good optical absorption properties with a band gap of 1.90 eV. The photo degradation rate of methyl violet solution over the title nanorods is 86%, which is significantly higher than that over commercial P25 (TiO2). The growth mechanism of the nanorod arrays completely follows the Ostwald ripening single crystal growth mechanism.