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高压热处理对Cu-37.67Zn-1.43Al合金导热及导电性能的影响
  • ISSN号:0258-7076
  • 期刊名称:《稀有金属》
  • 时间:0
  • 分类:TG379[金属学及工艺—金属压力加工] TG132.3[金属学及工艺—合金;一般工业技术—材料科学与工程;金属学及工艺—金属学]
  • 作者机构:[1]北华航天工业学院材料工程学院,河北廊坊065000, [2]华南理工大学国家金属材料近净成形工程技术研究中心,广东广州510640, [3]燕山大学材料科学与工程学院,河北秦皇岛066004
  • 相关基金:河北省自然科学基金(E2013409002); 华南理工大学国家金属材料近净成形工程技术研究中心开放基金(2011010); 河北省教育厅科研基金(QN2014031,QN20131117和Z2014086); 河北省高校百名优秀创新人才(BR2-239); 河北省普通高等学校青年拔尖人才计划项目(BJ2014001); 廊坊市科技支撑计划课题(2014011006,2014011010和2013011010); 廊坊市科技局研究课题(2011023130); 北华航天工业学院科研基金(KY-2014-06和KY-2014-24)资助
中文摘要:

采用热常数测试仪和电导仪测试了Cu-37.67Zn-1.43Al合金经1~5 GPa,700℃保温20 min处理前后的热导率和电导率,用光学显微镜和透射电镜对其组织特征进行观察,并探讨了高压热处理对Cu-37.67Zn-1.43Al合金导热性能和导电性能的影响。结果表明:退火态Cu-37.67Zn-1.43Al合金的原始组织由α相和少量的β相组成。经高压热处理后,合金组织中白色块状α相数量减少,出现细条状α相,组织明显细化,细化效果随压力的增大先增强后减弱,当压力为3 GPa时,组织细化效果最好。并且,高压热处理能降低Cu-37.67Zn-1.43Al合金的热导率和电导率,在1~5 GPa范围内,随着压力的增大,该合金的热导率和电导率均先降低后升高;压力为3 GPa时,热导率和电导率均达到最低值,分别为99 W·m-1·K-1和20.86%IACS,较高压处理前分别降低了14.66%和15.07%,但经高压处理与未经高压处理的样品热导率差值随着温度的升高而逐渐减小,在25℃时,两者的差值为17 W·m-1·K-1,而在400℃时,两者的差值为4 W·m-1·K-1。其原因主要是高压热处理后Cu-37.67Zn-1.43Al合金组织细化及组织内位错密度增大。

英文摘要:

The thermal conductivity and electrical conductivity of Cu-37.67Zn-1.43A1 alloy before and after heat treatment at 1 - 5 GPa and 700 ℃ for 20 rain were measured by thermal constant tester and electric conductivity instrument, the microstructure was ob- served by means of optical microscope (OM) , transmission electronic microscope ( TEM ) , and the effect of high pressure heat treat- ment on thermal conductivity and electrical conductivity of Cu-37.67Zn-1.43A1 alloy were investigated. The results showed that the o- riginal microstructure of annealed Cu-37.67Zn-1.43A1 alloy was composed of c~ phase and a small amount of β phase. After high pres-sure heat treatment, the number of white massive a phases reduced, thin strips a phase appeared, the microstructure was obviously re- fined, and the refinement effect increased with the pressure increasing firstly and then decreased. When the pressure was 3 GPa, the refinement effect was the best. The high pressure heat treatment could reduce the thermal conductivity and electrical conductivity of the alloy, and the thermal conductivity and electrical conductivity firstly decreased and then increased as the pressure increased under 1 ~ 5 GPa pressure. The thermal conductivity and electrical conductivity reached the minimum values of 99 W·m-1.K-l and 20.86% IACS under 3 GPa, respectively, decreasing by 14.66% and 15.07%, respectively, compared with those of the alloy without high pressure treatment, but the margin values of their thermal conductivity decreased gradually as the temperature increased, which were 17 W'm-I.K-1 at 25 ~C and 4 W.m-I.K-1 at 400 ~C, respectively. The main reason was that the microstructure was refined and the dislocation density within the grains of the alloy increased due to high pressure heat treatment.

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期刊信息
  • 《稀有金属》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:北京有色金属研究总院
  • 主编:屠海令
  • 地址:北京新街口外大街2号
  • 邮编:100088
  • 邮箱:xxsf@grinm.com
  • 电话:010-82241917 62014832
  • 国际标准刊号:ISSN:0258-7076
  • 国内统一刊号:ISSN:11-2111/TF
  • 邮发代号:82-167
  • 获奖情况:
  • 中文核心期刊,冶金工业类核心期刊,中国科技论文统计源期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:13688