在不同的衬底温度下,用脉冲激光沉积(PLD)方法制备了C轴高度取向的ZnO薄膜.采用同步辐射掠入射X射线衍射(GID)技术研究了ZnO薄膜与Si(111)衬底的界面结构.GID结果表明:不管衬底温度是500℃还是300℃,在无氧气氛下用PLD方法制备的ZnO外延膜均处于压应力状态,且随着X射线探测深度的增加,应力增大.结合常规X射线衍射技术,计算了薄膜内的双轴应力;给出了样品的泊松比和c/a值,得出两样品均接近理想的六方密堆积结构,偏离标准的ZnO值.综合各方面实验结果,说明衬底温度控制在500℃时生长的ZnO薄膜具有较好的晶体质量.
High-quality c-axis oriented ZnO thin films are grown on Si(111) substrates at different substrate temperatures by pulsed laser deposition. Synchrotron radiation X-ray grazing incident diffraction (GID) is employed to study the interface structure of ZnO/Si(111). GID results indicate that there is a compressive stress in all ZnO epitaxial films grown at substrate temperatures of 500 or 300℃ by PLD. With the increase of X-ray detection depth, the compressive stress increases. Combined with conventional XRD technology, the biaxial stress, Possion's ratio, and c/a of the ZnO films are calculated. The two sam- ples have a six-sided closed packing structure,deviating from the value of the standard ZnO. This indicates that the sample grown at 500~C has better crystal quality.