欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
合成了两种新型蒽醌单体：1,4-二（辛氧基）蒽-9,10-二酮和1,4-二（丁氧基）蒽-9,10-二酮。通过红外、核磁和元素分析确证了单体的结构。DSC、TG结果显示两种新型单体的5%质量损失温度最高可达266.4℃。将新型蒽醌单体与均苯四甲酸酐在硝基苯中预聚,再将预聚产物在NaCl/AlCl3熔盐中继续反应得到改性多省并醌聚合物。通过红外光谱、热分析等方法表征改性聚合物的结构并研究了改性聚合物的介电性能。研究结果表明改性聚合物仍有较好的热稳定性,5%质量损失温度〉387℃;20Hz下改性聚合物的最大介电常数值为100,比改性前低。同时合成了乙醇可溶的改性多省并醌聚合物,20Hz下最大介电常数为19997。
英文摘要：
Two new monomers of anthraquinone 1,4-bis（octyloxy） anthracene-9, 10-dione and 1,4-dibutoxyan thracene-9,10-dione were synthesized and characterized by FT-IR, 1 H NMR spectra and elemental analysis. Re- suhs of DSC and TG indicate melting points of two monomers are blow 130℃ and the 5% thermal decomposi tion temperatures are more than 200℃. The modified PAQR were obtained by step-growth condensation poly merization which the monomers react in nitrobenzene and then the unpurified products are dried and react in NaCl/AlCl3. The structure and thermal properties are characterized by FT-IR, TG. And the dielectric constant was studied,too. The modified PAQR still exhihits excellent thermal stability as the 5 % decomposition temper atures were over 387℃. The maximum of dielectric constant was 100 at 20Hz, which is less than the one of un modified PAQR. A class of modified polymer which was soluble in ethanol is obtained and the dielectric con stant was around 19997.
同期刊论文项目
同项目期刊论文
Study?on?temperature?characteristics?of?organic?light-emitting?diodes?based?on?tris-(8-hydroxylquino
Efficient Blue Organic Light-emitting Diodes with Simple Structure Based on N,N'-bis(1-naphthy)-N,N'
Efficient white organic light-emitting devices using a thin 4,4'-bis(2,2'-diphenylvinyl)-1,1'-diphen
Self-assembly of Tio2/polypyrrole nanocomposite ultrathin films and application for an NH3 gas senso
Luminescent Enhancement of Heterostructure Organic Light-Emitting Devices Based on Aluminum Quinolin
Influences of fluorine auxochrome in fluorene molecular electroluminescent material on optoelectroni
Efficient bright white organic light-emitting diode based on non-doped ultrathin 5,6,11,12-tetraphen
Fabrication and nonlinear optical properties of polymeric thin films doped with a novel tricyanofura
Low roll-off power efficiency of organic light-emitting diodes consisted of nondoped ultrathin phosp
X-ray photoelectron spectroscopy characterization of the interface between Ag electrode and PVDF fil
Spectral Characteristics of White Organic Light-emitting Diodes Based on Novel Phosphorescent Sensit
Color-tunable organic light-emitting devices using a thin N,N prime -bis-(1-naphthyl)-N,N prime -dip
Electron irradiation effects on the properties of heavily phosphorus-doped a-Si ,H films prepared fr
Efficeng small molecular and polymer organic devices using bis[2-(4-tert-butylpheny)benzothiazolato-
Study on tempeature characteristica of organic light-emitting diodes based on tris-(8-hydrocylquinol
Influence of PVK: NPB hole transporting layer on the charcateristics of organic light-emitting devic
Conducting polymericnanoparticles synthesized in reverse micelles and their gas sensitivity based on
Low energy emission bands in a small molecular fluorene derivative for organic light-emitting dioeds
Fiexible organic light-emitting diodes with improved performance by insertion of an UV-sensitive lay
期刊信息
位置：