以PAN基碳纤维为载体,采用溶胶-凝胶法制备碳纤维负载TiO2的光催化材料(TiO2/CF),用常温氧化-还原法在其表面沉积贵金属Pd粒子对其改性,制备碳纤维负载Pd-TiO2的光催化材料(Pd-TiO2/CF)。XRD分析表明:采用溶胶-凝胶法在碳纤维表面形成了锐钛矿型TiO2。选择偶氮类染料酸性橙Ⅱ作为光催化降解目标物,用紫外吸收光谱分析等TiO2负载量的TiO2/CF,Pd-TiO2/CF和粉末型TiO2的光催化活性。结果表明:TiO2在负载条件下光催化活性有所下降;Pd粒子沉积可有效提高光催化活性;对于酸性橙Ⅱ溶液,Pd-TiO2/CF光催化活性较TiO2/CF、 粉末型TiO2均有显著提高
Carbon-fiber-supported TiO2 photocatalytic material (TiO2/CF) was prepared by sol-gel method with PAN-based carbon fibers as support. Then the TiO2/CF was modified by depositing noble metal Pd particles on its surface by oxidation-redox method at room temperature to obtain carbon-fiber-supported Pd-TiO2 photocatalytic material (Pd-TiO2/CF). XRD analysis shows that TiO2 of anatase was formed on the surface of carbon fibers by sol-gel method. Acid orange II of azo dyes was chosen as the target of photocatalytic degradation, and the photocatalytic activities of TiO2/CF, Pd-TiO2/CF and powder TiO2 of equal load capacity were analyzed by UV absorption spectrum. The results indicate that the photocatalytic activity of powder TiO2 decreased to some extent under the supported condition; Pd particle deposition increased photocatalytic activity efficiently; the Pd-TiO2/CF has much higher photocatalytic activity for Acid orange II solution than TiO2/CF and powder TiO2