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基于SnO2-In2O3复合纳米纤维的薄膜型甲醛传感器研究
  • ISSN号:0253-3820
  • 期刊名称:《分析化学》
  • 时间:0
  • 分类:O631[理学—高分子化学;理学—化学]
  • 作者机构:[1]河南城建学院能源与建筑环境工程学院,平顶山467036, [2]江苏大学汽车与交通工程学院,镇江212013
  • 相关基金:本文系国家自然基金项目(Nos.50376021,50776042),河南省高等学校青年骨干教师资助项目(No.2010GGJS-150),河南省科技厅重点攻关计划项目(No.112102210363)资助
中文摘要:

采用双喷嘴静电纺丝技术制备了SnO2/In2O3复合纳米纤维,涂敷于带有金电极的氧化铝陶瓷管表面形成敏感薄膜,设计了一种新型薄膜型甲醛传感器。采用X射线衍射仪、热场发射扫描电子显微镜、O2-程序升温脱附仪和X-射线光电子能谱(XPS)仪,表征了SnO2/In2O3纳米纤维的相组成和微观形貌,分析了敏感薄膜成分配比对甲醛吸附强度与电化学的影响机理。在气体传感器静态测试系统上,采用XEDWS-60A型气敏元件分析仪测试了甲醛传感器敏感特性、温度特性、湿度特性、动态响应、抗干扰和稳定性。结果表明,以S50纳米纤维为敏感薄膜(膜厚为240nm)的甲醛传感器,在温度为500℃,甲醛浓度为0.5~50mg/L时,传感器线性度和灵敏度最大值分别为96.8%和97.5%,承受的温度上限为1000℃,动态响应和恢复时间分别为23和12s。此传感器对CO、NO。甲苯、菲、丙酮和甲醇等气体具有良好的抗干扰性能。在汽车上连续使用12个月后,响应衰减了5.5%,响应正常时间为6.4个月。

英文摘要:

SnO2-In2O3 composite nanofibers of formaldehyde sensor were prepared by the double jets electrospinning method. A new film-type formaldehyde sensor was designed with SnO2-In2O3 composite nanofibers transferred onto an alumina ceramic tube with Au electrodes. The crystalline phase and microstructure of SnO2-In2O3 composite nanofibers were displayed using X-ray diffraction (XRD) and field emission scanning electron microscope (FE-SEM), formaldehyde adsorption intensity and electrochemical mechanism of SnO2-In2O3 composite nanofibers were analyzed by oxygen temperature programmed desorption (O2-TPD) and X-ray photoelectron spectroscopy (XPS). These characteristic tests of formaldehyde sensor were carried out on the traits of sensitive performance, temperature, relative humidity, dynamic response, interference and stability by the XEDWS-60A type muhifunction analyzer in gas sensor static test system, the results demonstrated that formaldehyde sensor based on S50 composite nanofibers with 240 nm sensitive film thickness, when the operating temperature was 500 ℃ and formaldehyde concentration was increased from 0.5 to 50 mg/L, the best linearity and sensitivity of formaldehyde sensor were 96.8% and 97.5% respectively, and its high temperature level was 1000 ℃, the dynamic response time and recover time of formaldehyde sensor were 23 and 12 s, respectively. This kind of sensor showed good anti-disturbance to these gases, such as CO, NOx, toluene, phenanthrene, acetone, and methanol. The response value of formaldehyde sensor was attenuated about 5. 5%, when formaldehyde sensor was applied continually on the automobile about 12 months, and its normal time was 6.4 months.

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期刊信息
  • 《分析化学》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院长春应用化学研究所
  • 主编:杨秀荣
  • 地址:长春市人民大街5625号
  • 邮编:130022
  • 邮箱:fxhx@ciac.ac.cn
  • 电话:0431-85262017
  • 国际标准刊号:ISSN:0253-3820
  • 国内统一刊号:ISSN:22-1125/O6
  • 邮发代号:12-6
  • 获奖情况:
  • 1999获首届国家期刊奖,2000年获中国科学院优秀期刊特别奖,2001年入选中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国乌利希期刊指南,美国剑桥科学文摘,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:52455