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低压化学气相沉积生长双层石墨烯及其电输运特性研究
  • ISSN号:0258-7076
  • 期刊名称:稀有金属
  • 时间:2013
  • 页码:583-589
  • 分类:O613.11[理学—无机化学;理学—化学]
  • 作者机构:[1]北京有色金属研究总院先进电子材料研究所,北京100088, [2]北京有色金属研究总院国家半导体材料工程研究中心,北京100088
  • 相关基金:国家自然科学基金项目(50932001,51102020)资助
  • 相关项目:铪基稀土金属多元氧化物高K栅介质的基础研究
中文摘要:

采用低压化学气相沉积法(LPCVD)以铜箔为生长衬底来制备石墨烯。XRD表征得石墨烯生长前后铜箔衬底主要为(100)晶面,而且铜箔在高温下退火晶粒明显长大有利于高质量石墨烯的生长。拉曼光谱表明所制备的石墨烯为双层结构。通过转移、刻蚀等工艺制备了石墨烯场效应晶体管(G-FET)原型器件,其转移特性曲线(IDS-VGS)表明所制备的石墨烯表现为P型输运特性。在器件中石墨烯的XPS图谱说明了石墨烯吸附有有机物基团,导致p型特性的部分原因。同时本文研究了真空退火对G-FET器件性能的影响,结果表明:退火温度为200℃时,G-FET的空穴载流子迁移率最佳;而随着温度增加,开关比(ON.OFFratio)在不断减小,载流子迁移率迅速在降低。

英文摘要:

In this report, a low pressure chemical vapor deposition (LPCVD) was developed for the growth of graphene on Cu foils. Cu foils with (100) orientation was clearly observed in X-ray diffraction (XRD) pattern and nothing changed before or after graphene growth; and copper grain grown up obviously at high temperature was found to benefit the growth of high-quality graphene. Raman spectra suggested that the deposited graphene films were of bilayer. The graphene field effect transistor (G-FET) model device was fab- ricated with graphene ribbon as channel by removal and lithographic process. The transfer characteristic curve (IDS-VGS) of the typi- cal G-FET device was analyzed and the prepared graphene represented p-type transport characteristic. XPS spectrum of graphene in the device suggested that the graphene adsorbed organic group to make the graphene display p-type characteristic. Meanwhile, the effect of the vacuum annealing on the characteristic of the G-FET device was studied. The results suggested the mobilities for hole carriers of G- FET achieved optimum when the devices were annealed at 200℃ in the vacuum; the ON-OFF ratio minished quickly along with the temperature. The mobilities of the graphene started to degrade rapidly after annealed at 200℃.

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期刊信息
  • 《稀有金属》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:北京有色金属研究总院
  • 主编:屠海令
  • 地址:北京新街口外大街2号
  • 邮编:100088
  • 邮箱:xxsf@grinm.com
  • 电话:010-82241917 62014832
  • 国际标准刊号:ISSN:0258-7076
  • 国内统一刊号:ISSN:11-2111/TF
  • 邮发代号:82-167
  • 获奖情况:
  • 中文核心期刊,冶金工业类核心期刊,中国科技论文统计源期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:13688