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MOCVD生长的InN薄膜中In分凝现象
  • ISSN号:1000-7032
  • 期刊名称:《发光学报》
  • 时间:0
  • 分类:O472.1[理学—半导体物理;理学—物理]
  • 作者机构:[1]南京大学物理系江苏省光电功能材料重点实验室,江苏南京210093
  • 相关基金::国家自然科学基金(60476030,60421003,60676057);“973”专项基金(2006CB604905,2006CB604907);新世纪优秀人才计划(NCET-05-0445);江苏省自然科学基金(BK2006126)资助项目
中文摘要:

利用金属有机物化学气相淀积(MOCVD)方法不同生长条件下在C面蓝宝石衬底上制备了InN薄膜,通过不同的物理表征手段研究了InN薄膜的物理性质,结果表明:合适的生长温度可以抑制InN薄膜表面分凝现象。研究认为较低的生长温度使作为N源的NH,分解率较低,In—N的成键可能性小,导致In在表面聚集出现分凝;而较高生长温度时,InN薄膜中In—N键能较小,易发生断裂,反应活性较强的N和H原子逸离薄膜表面,In滞留在薄膜表面也导致In分凝现象的出现。相对于表面分凝的样品,未出现表面分凝的样品的薄膜晶体质量和表面形貌也得到了提高。同时,通过Raman散射谱研究了晶格振动E2声子模的应力效应。

英文摘要:

InN materials have been attracting a lot of attention for its prominent application in electronic and optical devices, compared with GaN and AlN, InN has smaller effective mass and higher electron drift velocity. However, the growth difficulties due to low growth temperature and lack of lattice-matched substrate restricted the evolution of InN-based devices, more and more efforts are made in efficiently deposit InN films with better quality. InN films were synthesized on the (0001) sapphire substrates at different growth temperatures by metal organic chemical vapor deposition (MOCVD), the growth source materials are trimethylindium (TMI), trimethylgallium(TMG) and ammonia( NH3 ). The physical properties of the films were characterized by a series of measurements. We fully studied the characteristic of InN films by various methods, such as X-ray diffraction (XRD), atomic force microscope (AFM), X-ray photoelectron spectroscopy (XPS) and Raman measurements. It's well known that the growth temperature is one of the most important parameters in InN films, so in our study, we focus our attention mainly on the effect of growth of temperature. It was found that 600 ℃ is a suitable growth temperature for InN films, the suitable temperature can inhibit the surface segregation phenomenon of In on the surface of InN films. But at a lower or higher temperature it will lead to a surface segregation of In on the InN films. The crystalline quality and morphology of the surface for the sample without surface segregation have been improved compared with the samples with surface segregation. In addition, it was also found that the residual strain in InN films increased with increasing growth temperature by Raman analysis, the E2 (high) model frequency shift toward high frequency with increasing growth temperature, and this shift is due to the presence of residual thermal strain in the InN film. When the growth temperature is lower, the residual thermal strain came into being due to the diffe

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期刊信息
  • 《发光学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国物理学会发光分会 中国科学院长春光学精密机械与物理研究所
  • 主编:申德振
  • 地址:长春市东南湖大路3888号
  • 邮编:130033
  • 邮箱:fgxbt@126.com
  • 电话:0431-86176862
  • 国际标准刊号:ISSN:1000-7032
  • 国内统一刊号:ISSN:22-1116/O4
  • 邮发代号:12-312
  • 获奖情况:
  • 物理学类核心期刊,2000年获中国科学院优秀期刊二等奖,中国期刊方阵“双效”期刊
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  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:7320