应用溶胶-凝胶法在Pt/Ti/SiO2/Si(001)基片上制备了BiFeO3薄膜,构架了Pt/BiFeO3/Pt电容器。采用X射线衍射仪和铁电测试仪研究了Pt/BiFeO3/Pt电容器的结构和物理性能。实验发现BiFeO3最佳的结晶温度为600℃,X射线衍射图谱显示BiFeO3薄膜结晶状况良好,原子力显微镜照片显示BiFeO3表面颗粒均匀。PL/BiFeO3/Pt电容器具有良好的电学性能,在驱动电压为5V的情况下,Pt/BiFeO3/Pt电容器的电滞回线具有良好的对称性,漏电流密度小于10^-4A/cm^2,研究发现BiFeO3薄膜log(J)/log(E)关系满足空间电荷限制电流传导机制。
Pt/BiFeO3/Pt ferroelectric capacitors have been fabricated on Pt/Ti/SiOz/Si substrates via a sol-gel method. X-ray diffraction technique and a ferroelectric tester were used to characterize the structural and physical properties of Pt/BiFeOa/Pt capacitors. It is found that the optimized temperature of BiFeO3 film is 600 ℃. The X-ray diffraction (XRD) measurement indicates that BiFeO3 film is well- crystalized. The atomic force microscopy (AFM) image indicates BiFeO3 film is dense with uniform grains. Hysteresis loop of Pt/BiFeO3/Pt capacitor, measured at 5 V, is very symmetric. Leakage current density of Pt/BiFeO3/Pt capacitor at 5 V is less than 10^-4A/cm^2, the relation of log(J) vs log(E) curve agrees well with the theory of space-charge-limited current.