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中文摘要：
目的合成介孔材料MCM-41-（CH_2）_3NH_2-EDTP,并初步研究其对水中铜离子吸附性能。方法以硅酸钠作为硅源,十六烷基三甲基溴化铵（CTAB）作为结构模板剂,在碱性条件下,利用水热法合成了纯硅源的MCM-41介孔分子筛。用3-氨丙基三乙氧基硅烷（APTES）和正硅酸乙酯（TEOS）对MCM-41介孔分子筛进行功能化修饰,成功得到了氨丙基修饰的MCM-41。将其与乙二胺四丙酸（EDTP）反应制得了MCM-41-（CH_2）_3NH_2-EDTP。采用X射线粉末衍射（XRD）和傅里叶红外光谱（FT-IR）表征手段对合成的新型功能化介孔材料进行表征。结果结果表明,MCM-41-（CH_2）_3NH_2-EDTP成功合成,乙二胺四丙酸改性的MCM-41对铜离子的吸附量明显高于纯MCM-41的吸附量。结论乙二胺四丙酸的成功嫁接使介孔材料在吸附性方面有很大提高,在水安全检测方面有很好的应用前景。
英文摘要：
Objective To study adsorption properties of Cu~（2＋） by functionalized mesoporous material MCM-41-（CH_2）_3NH_2-EDTP. Methods The MCM-41 were synthesized by hydrothermal method under alkaline conditions, using sodium silicate as source of silicon and cetyltrimethyl ammonium bromide as template. The modified MCM-41-（CH_2）_3NH_2 was modified by 3-aminopropyltrimethoxysilane（APTS） and ethylsilicate（TEOS）, then reacted with EDTP, which succeeded to obtain MCM-41-（CH_2）_3NH_2-EDTP. Assemblies were characterized by XRD, FT-IR and the adsorption of Cu~（2＋） were preliminary investigated. Results The adsorption of Cu~（2＋） by modified-EDTP MCM-41 was better than the adsorption of pure MCM-41. Conclusion After EDTP modified, the adsorption capacity can be improved obviously. The functionalized mesoporous material MCM-41-（CH_2）_3-EDTP has a promising prospect in inspection of water safety.
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