利用高频感应熔炉制备摩尔比率为75%La(Ni0.85Co0.15)5-x(Mn0.4Al0.3)x+12.5%Mg2Ni(x=0, 0.3,0.6)合金,测试合金的储氢性能,分析Mn、Al元素组合对合金储氢性能的影响.结果发现,合金均由多相组成,其中主相分别是CaCu5型的LaNi5相和PuNi3型的(La,Mg)Ni3相.随着元素(Mn,Al)含量增大,合金电极的循环稳定性有一定的改善,80次循环放电容量保持率从x=0时的59.1%提高到x=0.6时的74.5%.
The 75%La(Ni0.85Co0.15)5-x(Mn0.4Al0.3)x+12.5%Mg2Ni(x=0,0.3,0.6)alloys were prepared by high frequency induction furnace and their hydrogen-storage characteristics were tested systematically.The result showed that the alloys consist of multi-phases,and the main phases were LaNi5 phase with a hexagonal CaCu5-type structure and LaNi3 phase with PuNi3-type structure,and the stability of charging-discharging cycle was improved as the content of metals(Mn,Al)increased.The discharge capacity retention after 80 charging-discharging cycles increased from 59.1%(x=0)to 74.5%(x=0.6).